Laying the Groundwork for a Tantalum Dearomatization Agent
Author:
Nichols-Nielander, Adam Christopher Milan, Department of Chemistry, University of Virginia
Nichols-Nielander, Adam Christopher Milan, Department of Chemistry, University of Virginia
Advisor:
Harman, Dean, Department of Chemistry, University of Virginia
Harman, Dean, Department of Chemistry, University of Virginia
Abstract:
Chapter 1 provides a brief description of the synthesis of the -basic dearomatization agents {Os(NH3)5}, {TpRe(CO)L} (L=tBuNC, PMe3, py, MeIm, and NH3) and {TpW(NO)(PMe3)}. It also submits a theoretical explanation for the phenomenon of dearomatization via back bonding. The basic principles for the synthesis of a dearomatization agent that have been derived from these past syntheses are discussed in the context of the characteristics that we hoped to design into a new tantalum based dearomatizing metal fragment.
Note: Abstract extracted from PDF text
Degree:
MS (Master of Science)
MS (Master of Science)
Language:
English
English
Rights:
All rights reserved (no additional license for public reuse)
All rights reserved (no additional license for public reuse)
Issued Date:
2010/08/01
2010/08/01