The Reactivity and Properties of Dihapto-Coordinated Phenols

Zottig, Victor Enrico

The Reactivity and Properties of Dihapto-Coordinated Phenols 499 views

Author

Zottig, Victor Enrico, Department of Chemistry, University of Virginia

Advisors

Harman, Dean , Department of Chemistry , University of Virginia
Hoffman, Paul , Department of Medicine , University of Virginia

Abstract

Coordination of phenol by the electron rich metal fragment {TpW(NO)(PMe 3 )} causes an enol to ketone tautomerization. The structural change of the phenol has a dramatic effect on the observed reactivity. The regioand stereochemistry of subsequent additions is influenced both sterically and electronically by the metal fragment.

Note: Abstract extracted from PDF text

Degree

PHD (Doctor of Philosophy)

Language

English

Rights

Issued Date

2011-08-01

Persistent Link

https://doi.org/10.18130/V38K0N

Suggested Citation

Zottig, Victor Enrico. The Reactivity and Properties of Dihapto-Coordinated Phenols. University of Virginia, Department of Chemistry, PHD (Doctor of Philosophy), 2011-08-01, https://doi.org/10.18130/V38K0N.

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