The Reactivity and Properties of Dihapto-Coordinated Phenols
Author:
Zottig, Victor Enrico, Department of Chemistry, University of Virginia
Zottig, Victor Enrico, Department of Chemistry, University of Virginia
Advisors:
Harman, Dean, Department of Chemistry, University of Virginia
Hoffman, Paul, Department of Medicine, University of Virginia
Harman, Dean, Department of Chemistry, University of Virginia
Hoffman, Paul, Department of Medicine, University of Virginia
Abstract:
Coordination of phenol by the electron rich metal fragment {TpW(NO)(PMe 3 )} causes an enol to ketone tautomerization. The structural change of the phenol has a dramatic effect on the observed reactivity. The regioand stereochemistry of subsequent additions is influenced both sterically and electronically by the metal fragment.
Note: Abstract extracted from PDF text
Degree:
PHD (Doctor of Philosophy)
PHD (Doctor of Philosophy)
Language:
English
English
Rights:
All rights reserved (no additional license for public reuse)
All rights reserved (no additional license for public reuse)
Issued Date:
2011/08/01
2011/08/01
