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Activation of Anisoles and Anilines with a Tungsten -Base654 views
Author
Salomon, Rebecca Jean, Department of Chemistry, University of Virginia
Advisors
Fraser, Cassandra L., Department of Chemistry, University of Virginia
Abstract
Chapter 1 includes an overview of the reactivity arenes as synthons in traditional organic chemistry. Typical reactivity of arenes, such as anisole and aniline require harsh reagents to overcome their aromatic stability and often generate aromatic products. Methods to overcome the aromatic stabilization commonly employ transition metals. This review will focus on methods that employ -coordination for the activation of anisole and aniline, specifically 6 -coordination of arenes to electron-deficient metal centers and 2 -coordination to electron-rich metal fragments.
Note: Abstract extracted from PDF text
Degree
PHD (Doctor of Philosophy)
Language
English
Rights
All rights reserved (no additional license for public reuse)
Salomon, Rebecca Jean. Activation of Anisoles and Anilines with a Tungsten -Base. University of Virginia, Department of Chemistry, PHD (Doctor of Philosophy), 2010-08-01, https://doi.org/10.18130/V3W82W.