An analysis of the electronic absorption and magnetic circular dichroism spectra of d-d transitions in the hexafluoroosmate (IV) and hexafluoroiridate (IV) ions

Author:
Weiss, Lucy Cline, Chemistry, University of Virginia
Advisors:
Richardson, Frederick, Chemistry, University of Virginia
Coleman, Robert V., Physics, University of Virginia
Schatz, Paul N., Chemistry, University of Virginia
Abstract:

An analysis of the low temperature, high resolution electronic absorption and magnetic circular dichroism spectra of d-d transitions in OsF 2-6 and IrF 2-6 (specifically, Os4+ and Ir 4+ doped into the cubic host Cs2 GeF6) is presented, and ligand field parameters are determined.

Degree:
PHD (Doctor of Philosophy)
Keywords:
Transition metal compounds--Spectra, Circular dichroism, Ligand field theory
Language:
English
Rights:
All rights reserved (no additional license for public reuse)
Issued Date:
1972